Couldn't we just build a MegaMaid and suck the atmosphere out? If we're going to go sci-fi, it seem easier to hoover it out than capture an asteroid and nick the atmosphere just right.
I’ve read that a large asteroid could be positioned at a particular Mars L point and it would protect the planets atmosphere from being stripped by the sun.
That would require a lot of energy to ensure the gasses escape Venus' gravitational pull, which would in turn effectively be a rocket. So then we'd be adjusting to ensure we don't mess with Venus' orbit too much.
Venus outweighs its atmosphere by about 10,000 times. This is actually less than I thought -- for comparison Earth outweighs its atmosphere by over 1,000,000 times, which is still far less than I would have guessed.
Venus's escape velocity is less than 1/3rd of its orbital velocity. According to google, Venus's orbit, despite being very circular, causes its velocity to vary by a KM/s from aphelion to perihelion.
So I believe you could send all of Venus's atmosphere off permanently into space at the cost of about 1/30,000th of Venus's orbital velocity, meaning you could very slightly circularize its orbit further.